Mechanism of dye solubilization and de-aggregation by urea

نویسندگان

چکیده

Urea is an effective solubilizer for dyes with low aqueous solubility. To establish, at a molecular level, the reason behind action of urea as solubilizer, we employ rigorous statistical thermodynamics approach based on Kirkwood-Buff theory solutions. We show that (i) contrary to classical hypothesis “water structure breaking”, effect dye hydration makes minor contribution solubilization; (ii) driving force solubilization accumulation around hydrophobic molecules. • Why was clarified using thermodynamics. The solubilization. molecules drives

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ژورنال

عنوان ژورنال: Dyes and Pigments

سال: 2021

ISSN: ['1873-3743', '0143-7208']

DOI: https://doi.org/10.1016/j.dyepig.2021.109530